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In page Metal L-edge:
"For a ferric system, all of these effects result in 252 initial states and 1260 possible final states that together will comprise the final L-edge spectrum (Figure 2e). Despite all of these possible states, it has been established that in a low-spin ferric system, the lowest energy peak is due to a transition to the t2g hole and the more intense and higher energy (~3.5 eV) peak is to that of the unoccupied eg orbitals.[1]
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