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In page Saccharin:

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Saccharin derives its name from the word "saccharine", meaning "sugary". The word saccharine is used figuratively, often in a derogative sense, to describe something "unpleasantly over-polite" or "overly sweet".[1] Both words are derived from the Greek word σάκχαρον (sakkharon) meaning "gravel".[2] Relatedly, saccharose is an obsolete name for sucrose (table sugar).