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In page Standard deviation:

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Unlike in the case of estimating the population mean, for which the sample mean is a simple estimator with many desirable properties (unbiased, efficient, maximum likelihood), there is no single estimator for the standard deviation with all these properties, and unbiased estimation of standard deviation is a very technically involved problem. Most often, the standard deviation is estimated using the corrected sample standard deviation (using N − 1), defined below, and this is often referred to as the "sample standard deviation", without qualifiers. However, other estimators are better in other respects: the uncorrected estimator (using N) yields lower mean squared error, while using N − 1.5 (for the normal distribution) almost completely eliminates bias.